Advanced carbon materials formed from abundant biomass are an exciting and promising class for energy devices due to the clear advantages of low cost, sustainability and good physical and electrochemical properties. However, these materials typically do not compete well with their metal functionalised counterparts. In this work, we demonstrate that xCo(OH) 2 –(1−x)Ni(OH) 2 with various Ni:Co ratios can be deposited onto biomass-derived carbon to make a hybrid inorganic-carbon electrode with tuneable physical features and electrochemical performance. These features were tuned by adjusting the Ni:Co ratio within precursor solutions. The electrodes had shown a capacitance ranging from 780.7 to 2041 F g −1 , which is very close to the theoretical value for Ni(OH) 2 (2365 F g −1 ). A hypothesis is presented to help explain this performance for a modified, biomass-derived carbon electrode.
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机译:由丰富的生物质形成的高级碳材料由于其低成本,可持续性以及良好的物理和电化学性能的明显优势,成为能源设备中令人兴奋且有希望的一类。但是,这些材料通常不能与金属功能化的同类产品很好地竞争。在这项工作中,我们证明可以将具有各种Ni:Co比率的xCo(OH)2 –(1-x)Ni(OH)2沉积到生物质衍生的碳上,从而制得具有可调节物理特性的杂化无机碳电极。电化学性能。通过调整前体溶液中的Ni:Co比例来调整这些功能。电极的电容范围为780.7至2041 F g -1,非常接近Ni(OH)2的理论值(2365 F g -1)。提出了一个假设,以帮助解释改性生物质衍生碳电极的这种性能。
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